By Hanna Dodiuk, Sydney H Goodman
ISBN-10: 0815514212
ISBN-13: 9780815514213
ISBN-10: 1591240948
ISBN-13: 9781591240945
Thermosetting plastics are a unique type of plastics whose excessive functionality, toughness and reliability at excessive temperatures makes them appropriate for area of expertise functions starting from automobile and aerospace via to digital packaging and patron items (your melamine kitchen worktop is a thermoset resin!). contemporary advancements in thermoset plastics know-how and methods has broadened their use exponentially over contemporary years, and those advancements proceed: in November 2011, French scientists created a brand new light-weight thermoset that's as powerful and strong as past fabrics but could be simply remodeled and reshaped while heated which makes it certain among thermosets and permits fix and recycling.
The guide of Thermoset Plastics, now in its 3rd variation, offers a complete survey of the chemical strategies, production suggestions and layout houses of every polymer, in addition to their functions. Written through a workforce of hugely skilled practitioners, the sensible implications of utilizing thermoset plastics are offered – either their strengths and weaknesses. the knowledge and outlines provided right here permit engineers, scientists and technicians to shape judgments and take motion at the foundation of proficient research. the purpose of the ebook is to assist the reader to make the precise choice and take the proper motion – averting the pitfalls the authors’ event has uncovered.
The new version has been up to date all through to mirror present perform in production and processing, featuring:
- Case stories to illustrate how specific homes make various polymers appropriate for various purposes, in addition to protecting end-use and protection considerations.
- A new bankruptcy on utilizing nanoparticles to reinforce thermal and mechanical properties.
- A new bankruptcy describing new fabrics in accordance with renewable assets (such as soy-based thermoset plastics).
- A new bankruptcy protecting contemporary advancements and power destiny applied sciences reminiscent of new catalysts for Controlled Radical Polymerization.
- Goodman and Dodiuk-Kenig offer a finished reference advisor to the chemistry, production and purposes of thermosets.
- Updated to incorporate contemporary advancements in production – from biopolymers to nanocomposites.
- Case experiences illustrate functions of key thermoset plastics.
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Additional info for Handbook of thermoset plastics
Example text
Unpreheated preforms (loose powder form) tend to absorb more water under humid conditions and will lose moisture and stiffen in low moisture or dry conditions such as in winter. It is recommended that phenolics be stored at room tempcraturc and 50 to 60% relative humidity. Good weather resistance. Phenolics can be used outdoors for short periods, but prolonged outdoor exposure to ultravioletlight and heat can cause failure. Good machining qualities. Machining qualities are fair to good for molding compounds but are excellent for casting resins.
The criteria used to establish thispoint aregenerallysuffkient “green”strengthof the part (canbe handled without deformation)and sufkient cum to miniize shrinkage(very little shrinkagestressor warpagewill set in beyondthis point). A cure scheduleis derivedby plotting the changein the plastics’ properties of interestagainsttime at temperatureand pressure. A sample curveis generatedlike the oneshownin Figure l-9. hactical considerations generallydictatethat the curetime be chosenat somefractional level of the ultimate properties.
The adhesive material for exterior grade plywood is resole-type phenolic resin with a swell-resistant tiller such as coconut shell. Other fillers used arc oat hulls, wheat flour, and chalk. Wheat flour and chalk are mainly used as extcnders for adhesiveness. The extenders are also used to reduce cost and porosity. Sodium hydroxide serves as a solubilizer in phenolic resin in water. Phenolic resins compete very favorably with urea-formaldehyde bonded plywood, and most of the plywood made today is phenolic resins based.
Handbook of thermoset plastics by Hanna Dodiuk, Sydney H Goodman
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