By K. Tanabe
ISBN-10: 0080887554
ISBN-13: 9780080887555
ISBN-10: 0444988009
ISBN-13: 9780444988003
This quantity summarises and experiences the big development remodeled the previous 20 years in reliable acids and bases, with emphasis on basic features and chemical rules. in recent times many new different types of stable acids and bases were discovered and synthesized. the outside houses (in specific, acidic and easy homes) and the buildings of the hot solids were clarified by way of newly built size equipment utilizing glossy tools and strategies. The characterised reliable acids and bases were utilized as catalysts for various reactions, many stable correlations being got among the acid-base homes and the catalytic actions or selectivities. lately, acid-base bifunctional catalysis on stable surfaces is turning into a a growing number of vital and fascinating box of analysis. it's been well-known that the acidic and simple homes of catalysts and catalyst helps play an incredible position in oxidation, aid, hydrogenation, hydrocracking, and so forth.
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Extra resources for New Solid Acids and Bases
Sample text
66) H O , ~ can = be regarded as a practical parameter to represent an acid-base property on solids which is sensitive to the surface structure. A solid with a large positive Ho,m= has strong basic sites and weak acidic sites. Thus, basic sites play an important role. On the other hand, a solid with a large negative H O , ~has = strong acidic sites and weak basic sites. In this case, acid sites often become important. 22 D E T E R M I N A T I O N OF ACIDIC A N D B A S I C PRUPEKTIES O N SOLID SIJRFACES A good linear relation was reported between H0,mU of A1203 - SiOz treated with fluorine and the catalytic activity for the synthesis of P-ethylpyridine from acrylaldehyde (Fig.
Catalysis, VerlagChemie, 1984, Val. 4, p. 507. 48. S. Malinowski, S. Szczepanska,J. , 2, 310 (1963). 49. K. Tanabe, T. Yamaguchi, J . Res. Insf. , 11, 179 (1964). 50. J . Take, N. Kikuchi, Y. Yoneda,]. , 21, 164 (1971). 51. G . Suzukamo, M . Fukao, M. Minobe, C h m . ,1987, 585. 52. H . Hattori, N. Yoshii, K. Tanabe, Proc. 5th Intern. Congr. Catalysis, 1972, 10-233. 53. K. Tanabe, K. Saito,J. , 35, 247 (1974). 54. V. A. Fokina, Problony Kincf. , Acad. Nauk, USSR,8, 248 (1955). 55. K. Tanabe, T.
A. J. Deyrup,]. Am Chcm. , 54, 2721 (1932). K. Tanabe, Solid Acidr and Bases, Kodansha, Tokyo and Academic Press, New York London, 1970. K. Tanabe, in Cafalysis: Science and Technology, (eds. R. Anderson and M. Boudart) Springer-Verlag. 2, Chapt. 5. K. Hattori, C h m . , 1976, 625. K. Shibata, T. Kiyoura, J. Kitagawa, T . Surniyoshi, K. Tanabe, Bull. Chcm. , 46,2985 (1973). S. P. B. Halgeri,]. Res. Insf. , 20, 219 (1972). L. Forni, Advan. , 8 , 65 (1974). K. Tanabe, T. Yamaguchi,J. Res. Insf. , 14, 93 (1966).
New Solid Acids and Bases by K. Tanabe
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