By Fairgrieve, Stuart
ISBN-10: 1847350836
ISBN-13: 9781847350831
ISBN-10: 1847351530
ISBN-13: 9781847351531
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Sample text
969480 Item 32 APT 05. 2005. 11, 29cm, ISBN 8391769348, 012 MICRONISED TALC AS NUCLEANT IN SEMICRYSTALLINE TECHNOPOLYMERS Malacari P E; Canalini G; leusciatti M IMI Fabi SpA (Torun,Institute of Plastics Processing; Gliwice,Institute of Plastics & Paint Industry) The efficiencies of talc and several other nucleating agents, including benzoates and sorbitol, in semi-crystalline polymers (PP, high-impact propylene copolymer, polyamide-6, polyamide-66, PBTP and PETP) were evaluated. The crystallisation temperature, crystallisation enthalpy, flexural properties and impact properties of the polymers were determined and the properties improved by the addition of nucleating agents identified.
E3B [Clariant] Quinacridone β nucleator. EC Series [EC Chemical] EC-1 - Dibenzylidene sorbitol. EC-4 - (4-Chlorobenzylidene)(4-methylbenzylidene) sorbitol. Gel All/Geniset Series [New Japan Chemical/Rika International] Gel All DX - Bis(3,4-dimethylbenzylidene) sorbitol. Gel All E200 – Sorbitol-based preparation (sic). Geniset D - Dibenzylidene sorbitol. Geniset MD - Bis(4-methylbenzylidene) sorbitol. Geniset MD-LM30 - Low melting preparation of MD. Hyperform Series [Milliken] Based on norbornane diacid salts.
The nanoparticles were coated with two types of compatibiliser (either polypropylene-g-maleic anhydride copolymer, or fatty acids) to improve dispersion and adhesion with the polymer matrix. It was found that the type of coating agent used largely affects the nucleating ability of calcium carbonate towards formation of polypropylene crystals. CaCO3 nanoparticles coated with maleated polypropylene can successfully promote nucleation of iPP crystals, whereas the addition of nanosized calcium carbonate coated with fatty acids delays crystallisation of iPP, the effect being mainly ascribed to the physical state of the coating in the investigated temperature range for crystallisation of iPP, as well as to possible dissolution by fatty acids of heterogeneities originally present in the polypropylene matrix.
Nucleating Agents by Fairgrieve, Stuart
by Christopher
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