By R Arshady; et al
ISBN-10: 0387571981
ISBN-13: 9780387571980
ISBN-10: 3540571981
ISBN-13: 9783540571988
A part of a multi-volume reference paintings on advancements in polymer technological know-how, this publication comprises examine papers on polymer synthesis through activated esters, the thermostability and liquid crystal homes of fragrant polyamides and reactive surfactants in emulsion polymerization
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Additional info for Polymer synthesis
Example text
Examples of such polymer obtained by active ester synthesis are illustrated in Fig. 20 [16]. Among the polymers represented in Fig. 20, the derivative 28a carries quinone groups, and is directly electroactive, whereas 28b-28d become electroactive following metal complexation. The polymers 28e-28f carry nitrogen ligands and halogen groups, and are precursor to multi-dentate amine/ phosphine ligands. -butoxide. Structures of a number of metal complexes (chelates, 29-33) obtained by reaction of these polymers with various metal substrates are shown in Fig.
Then under certain special stresses, they can be desorbed and their stabilizing properties are lost; it may be the case under shear stresses, eventually during the polymerization if the stirring conditions are not adequate. It is also the case in cycles of freezing and thawing. Flocculation occurs and peptization of the floes is not always possible. When films are formed from the latexes, as for use in paints, textile treatments, paper coatings or adhesives, the coalescence may be partially hindered, and then delayed, and when it takes place, the surfactants remain in the concentrated water phase and, the major part of them remains in hydrophilic domains buried inside thefilms,even if some part is expelled toward the surface of the film.
Plenum, New York 6. Arshady R (1989) Polym Eng Sci 29: 1746; (1990) Polym Eng Sci 30: 905 and 915 7. Arshady R (1991) J Chromatogr 586: 181 and 199 8. Shalaby WS, McCormic L, Butler B (eds) (1991) Water-soluble polymers: Synthesis, solution properties and applications, ACS Symp Ser 467 9. Harland RS, Prud'homme RK (1992) Polyelectrolyte gels: Properties, preparation, and applications, ACS Symp Ser 480 10. DeRossi D, Kajiwara K, Osada Y, Yamauchi A (eds) (1991) Polymer gels. Plenum, New York 11.
Polymer synthesis by R Arshady; et al
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