By Dr. L. Jansen (auth.)
ISBN-10: 9401756848
ISBN-13: 9789401756846
ISBN-10: 9401759928
ISBN-13: 9789401759922
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Extra info for Some Aspects of Molecular Interactions in Dense Media
Example text
6 and 7). To explain the deviations at low densities (up to 200 Amagat) we calculate the average change in the polarizability, leaving the values of C I and C2 open. 49. From a comparison between the values in the table and the deviations between the statistical theory and the experimental values for the Clausius-Mosotti and Lorentz-Lorenz functions we deduce that C I + 3C2 ~ I, which is of the same order of magnitude as for helium (C I + 3C2 = 165/128). It may therefore be expected that the theory presented in this paper will improve *) The Lorentz-Lorenz expression may also be taken for the comparison between the statistical theory and the experimental results because-the effect of dispersion is probably very small.
Physic a lil (1949) 769. 4) Kirkwood, ]. , J. Chern. 4(1936) 592. , J. Chern. Phys. 18 (1950) 1193, 1200. , deB 0 e r, J. , PhY,sica 4 (1937) 981. 7) de Groot, S. R. and ten Seldam, C. , Physica 1:1 (1947) 47; 18 (1952) 905,910; ten S e J dam, C. , Thesis, Utrecht (1953). 8) Chapter I OI this thesis. , van der l\laesen, F. and ten Seldam, C. , Physica II} (1933) 265. 10) tell Seldam, C. A. and de Groot, S. K, Physica 18 (1952) 910; ten Seldam, C. , Thesis, Utrecht, 1953. 29 CHAPTER III DEVIATIONS FROM ADDITIVITY OF THE INTERMOLECULAR FIELD AT HIGH DENSITIES ยง 1.
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Some Aspects of Molecular Interactions in Dense Media by Dr. L. Jansen (auth.)
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